资源类型

期刊论文 143

年份

2023 20

2022 17

2021 20

2020 9

2019 7

2018 14

2017 12

2016 2

2015 6

2014 4

2013 1

2012 2

2011 4

2010 7

2009 6

2008 1

2007 5

2001 1

2000 1

展开 ︾

关键词

二氧化碳 2

&alpha 1

一氧化碳 1

一维（1D） 1

两亲高分子 1

乙烷干重整 1

产氧反应 1

产氧缝合线 1

亲水 1

伤口 1

催化剂 1

全层氧气递送 1

共混微孔膜 1

内部取代BN 1

助催化剂 1

化学循环 1

医院中子照射器 1

协同效应 1

双金属羟基氧化物 1

展开 ︾

检索范围：

排序： 展示方式：

Experimental investigation on possibility of oxygen enrichment by using gradient magnetic fields

CAI Jun, WANG Li, TONG Lige, SUN Shufeng, WU Ping

《化学科学与工程前沿（英文）》 2007年 第1卷 第3期   页码 271-276 doi: 10.1007/s11705-007-0049-x

摘要： This paper presents a novel method that uses the interception effect of gradient magnetic field on oxygen molecules to realize enrichment. The use of two opposite magnetic poles of two magnets at a certain distance forms a magnetic space having a field intensity gradient near its borders. When air injected into the magnetic space outflows from the magnetic space via its borders, oxygen molecules in the air will experience the interception effect of the gradient magnetic field, but nitrogen molecules will outflow from the magnetic space without hindrance. Thus, continuous oxygen enrichment is realized. The enrichment degree of oxygen reaches 0.65% when the inlet and outlet air flows are 40 mL/min and 20 mL/min, respectively, and the gas temperature is 298 K and the maximal product of magnetic flux density and its gradient is 563 T/m (the distance between two magnetic poles is 1 mm). When the gas temperature rises to 343 K, the enrichment degree drops to 0.32%; and when the maximal product of magnetic flux density and field intensity gradient drops to 101 T/m (the distance between two magnetic poles is 4 mm), the enrichment degree drops to 0.23%. The experimental results show that there is an optimal ratio between the inlet air flow and the outlet air flow. Under the experimental conditions in this paper, the value is about 2.0. It is demonstrated that the method presented in this paper can continuously enrich oxygen and has a higher enrichment degree than other oxygen-enrichment methods using magnetic separation.
HTML PDF 收藏

using tower bipolar electro-flocculation including the removal of phosphorus, turbidity, sulfion, and oxygenenrichment

Huan He, Qinjin Yu, Chaochao Lai, Chen Zhang, Muhan Liu, Bin Huang, Hongping Pu, Xuejun Pan

《环境科学与工程前沿（英文）》 2021年 第15卷 第2期 doi: 10.1007/s11783-020-1310-5

摘要： Abstract • An innovative bubble column tower BPE was designed to treat the black-odorous water. • PO43−, S2− and turbidity were removed, and dissolved oxygen was enriched in the BPE. • An aluminum bipolar electrode gave the best oxygen enrichment and pollutant removal. • Changes of microorganisms confirmed the improvement in water quality achieved. The large amount of municipal wastewater discharged into urban rivers sometimes exceeds the rivers’ self-purification capacity leading to black-odorous polluted water. Electro-flocculation has emerged as a powerful remediation technology. Electro-flocculation in a bubble column tower with a bipolar electrode (BPE) was tested in an attempt to overcome the high resistance and weak gas-floatation observed with a monopolar electrode (MPE) in treating such water. The BPE reactor tested had a Ti/Ta2O5-IrO2 anode and a graphite cathode with an iron or aluminum bipolar electrode suspended between them. It was tested for its ability to reduce turbidity, phosphate and sulphion and to increase the concentration of dissolved oxygen. The inclusion of the bipolar electrode was found to distinctly improved the system’s conductivity. The system’s electro-flocculation and electrical floatation removed turbidity, phosphate and sulphion completely, and the dissolved oxygen level improved from 0.29 to 6.28 mg/L. An aluminum bipolar electrode performed better than an iron one. Changes in the structure of the microbial community confirmed a significant improvement in water quality.

关键词： Black-odorous water     Bipolar electrodes     Flocculation     Floatation     Oxygen enrichment     Turbidity    

HTML PDF 收藏

Water Diversion is Not to Blame for Phosphorus Enrichment in Taihu Lake

Zhiyuan Wang,Qiuwen Chen,Jianyun Zhang,Hanlu Yan,

《工程（英文）》 doi: 10.1016/j.eng.2023.07.007

摘要： The Water Diversion Project from the Yangtze River to Taihu Lake (WDYT) has been widely recognized as an urgent and effective engineering measure to increase water resources, ameliorate the hydrodynamics and water quality conditions, and safeguard the water supply of Taihu Basin. However, some previous studies claimed that WDYT has brought in allochthonous nutrients and should take responsibility for the dramatic increase in phosphorus loading of Taihu Lake in recent years, because Yangtze River has a higher average phosphorus concentration than Taihu Lake. To ensure correct public understanding and provide a critical response to the misconception about the source of phosphorus loading, we quantified contribution of water diversion from the Yangtze River to phosphorus loadings of Taihu Lake over the past twenty years. We reveal that WDYT only diverted 4.3% annually of total phosphorus input of Taihu Lake in the last decade and should not be responsible for the increase in phosphorus concentration and loading in Taihu Lake. We conclude that phosphorus input from the Huxi Region contribute 78% of phosphorus input of Taihu Lake and should be primarily responsible for the high phosphorus concentration of Taihu Lake. Our findings have provided constructive guidance for water resource management of Taihu Basin and phosphorus load control of the second stage of WDYT.
HTML PDF 收藏

the effect of nitrogen on mixed culture polyhydroxyalkanoate production toward high organic loading enrichment

Zhiqiang Chen, Lizhi Zhao, Ye Ji, Qinxue Wen, Long Huang

《环境科学与工程前沿（英文）》 2019年 第13卷 第4期 doi: 10.1007/s11783-019-1135-2

摘要：

Effect of nitrogen on mixed culture PHA production was reconsidered.

Enrichment history of PHA accumulating culture was discussed.

Higher PHA content and biomass growth were achieved in presence of nitrogen.

Enrichment strategy toward higher PHA accumulation was investigated.

Microbial community succession in PHA accumulation phase was investigated.

关键词： Polyhydroxyalkanoate (PHA)     Organic loading rate     Nitrogen content     Biomass growth     Enrichment history    

HTML PDF 收藏

Heterometallic cluster-based organic frameworks as highly active electrocatalysts for oxygen reductionand oxygen evolution reaction: a density functional theory study

《化学科学与工程前沿（英文）》 2023年 第17卷 第5期   页码 570-580 doi: 10.1007/s11705-022-2247-y

摘要： Recently, metal–organic frameworks are one of the potential catalytic materials for electrocatalytic applications. The oxygen reduction reaction and oxygen evolution reaction catalytic activities of heterometallic cluster-based organic frameworks are investigated using density functional theory. Firstly, the catalytic activities of heterometallic clusters are investigated. Among all heterometallic clusters, Fe2Mn–Mn has a minimum overpotential of 0.35 V for oxygen reduction reaction, and Fe2Co–Co possesses the smallest overpotential of 0.32 V for oxygen evolution reaction, respectively 100 and 50 mV lower than those of Pt(111) and RuO2(110) catalysts. The analysis of the potential gap of Fe2M clusters indicates that Fe2Mn, Fe2Co, and Fe2Ni clusters possess good bifunctional catalytic activity. Additionally, the catalytic activity of Fe2Mn and Fe2Co connected through 3,3′,5,5′-azobenzenetetracarboxylate linker to form Fe2M–PCN–Fe2M is explored. Compared with Fe2Mn–PCN–Fe2Mn, Fe2Co–PCN–Fe2Co, and isolated Fe2M clusters, the mixed-metal Fe2Co–PCN–Fe2Mn possesses excellent bifunctional catalytic activity, and the values of potential gap on the Mn and Co sites of Fe2Co–PCN–Fe2Mn are 0.69 and 0.70 V, respectively. Furthermore, the analysis of the electron structure indicates that constructing a mixed-metal cluster can efficiently enhance the electronic properties of the catalyst. In conclusion, the mixed-metal cluster strategy provides a new approach to further design and synthesize high-efficiency bifunctional electrocatalysts.

关键词： bimetallic metal–organic frameworks     bifunctional electrocatalyst     density functional theory     oxygen reduction reaction     oxygen evolution reaction    

HTML PDF 收藏

Enrichment and transfer of polycyclic aromatic hydrocarbons (PAHs) through dust aerosol generation from

《环境科学与工程前沿（英文）》 2023年 第17卷 第1期 doi: 10.1007/s11783-023-1610-7

摘要：

● Compositional patterns of PAHs in dust aerosol vary from soil during dust generation.

关键词： Dust aerosols     Enrichment factors (EFs)     Polycyclic aromatic hydrocarbons (PAHs)    

HTML PDF 收藏

Mercury enrichment in

Chunhao Dai, Pufeng Qin, Zhangwei Wang, Jian Chen, Xianshan Zhang, Si Luo

《环境科学与工程前沿（英文）》 2017年 第11卷 第1期 doi: 10.1007/s11783-017-0892-z

摘要： Mercury enrichment in response to elevated atmospheric mercury concentrations in the organs of rape ( ) was investigated. Elevated soil mercury content had significant impact on mercury accumulation in rape stems, roots, seeds and seed coats. Leaf mercury in the leaves was mostly affected by atmospheric input while the stems were mostly affected by soil concentrations. Mercury in the aboveground plant tissue mainly derived from atmospheric absorption, and atmospheric mercury absorption in leaves was higher than that in the stems. Mercury enrichment in response to elevated atmospheric mercury concentrations in the organs of rape ( ) was investigated using an open top chamber fumigation experiment and a soil mercury enriched cultivation experiment. Results indicate that the mercury concentration in leaves and stems showed a significant variation under different concentrations of mercury in atmospheric and soil experiments while the concentration of mercury in roots, seeds and seed coats showed no significant variation under different atmospheric mercury concentrations. Using the function relation established by the experiment, results for atmospheric mercury sources in rape field biomass showed that atmospheric sources accounted for at least 81.81% of mercury in rape leaves and 32.29% of mercury in the stems. Therefore, mercury in the aboveground biomass predominantly derives from the absorption of atmospheric mercury.

关键词： Open top chamber     Gaseous elemental mercury (GEM)     Soil Mercury     Brassica napus    

HTML PDF 收藏

Interface engineering for enhancing electrocatalytic oxygen evolution reaction of CoS/CeO heterostructures

《化学科学与工程前沿（英文）》 2022年 第16卷 第3期   页码 376-383 doi: 10.1007/s11705-021-2062-x

摘要： To realize renewable energy conversion, it is important to develop low-cost and high-efficiency electrocatalyst for oxygen evolution reaction. In this communication, a novel bijunction CoS/CeO2 electrocatalyst grown on carbon cloth is prepared by the interface engineering. The interface engineering of CoS and CeO2 facilitates a rapid charge transfer from CeO2 to CoS. Such an electrocatalyst exhibits outstanding electrocatalytic activity with a low overpotential of 311 mV at 10 mA∙cm−2 and low Tafel slope of 76.2 mV∙dec–1, and is superior to that of CoS (372 mV) and CeO2 (530 mV) counterparts. And it has long-term durability under alkaline media.

关键词： interface engineering     CoS/CeO2     electrodeposition     electrocatalyst     oxygen evolution reaction    

HTML PDF 收藏

页岩气主要富集因素与核心区选择及评价

王社教,杨涛,张国生,李登华,陈晓明

《中国工程科学》 2012年 第14卷 第6期   页码 94-100

摘要：

影响页岩气规模开发的因素很多，最核心的因素是首先要通过建立地质评价标准，选出页岩气核心区。核心区的确定关系到在页岩气勘探初期，是否能找准页岩气最富集的目标，选择最有利地区进行勘探，突破出气关，进而实现大规模经济开发。从页岩气成藏特征、页岩气富集因素分析入手，重点探讨我国富有机质页岩的丰度、成熟度、脆性矿物含量、含气性以及盖层等关键参数及其作用。借鉴北美页岩气勘探开发和研究成果，结合我国页岩气勘探开发和研究新进展，初步建立我国页岩气核心区地质评价标准，并优选出我国南方海相页岩气的核心区，指出四川盆地南部是我国最现实的页岩气开发区。

关键词： 核心区     选区与评价     富集因素     海相页岩     页岩气    

HTML PDF 收藏

High-entropy catalysts for electrochemical water-electrolysis of hydrogen evolution and oxygen evolution

《能源前沿（英文）》 doi: 10.1007/s11708-023-0892-6

摘要： High entropy materials (HEMs) have developed rapidly in the field of electrocatalytic water-electrolysis for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) due to their unique properties. In particular, HEM catalysts are composed of many elements. Therefore, they have rich active sites and enhanced entropy stability relative to single atoms. In this paper, the preparation strategies and applications of HEM catalysts in electrochemical water-electrolysis are reviewed to explore the stabilization of HEMs and their catalytic mechanisms as well as their application in support green hydrogen production. First, the concept and four characteristics of HEMs are introduced based on entropy and composition. Then, synthetic strategies of HEM catalysts are systematically reviewed in terms of the categories of bottom-up and top-down. The application of HEMs as catalysts for electrochemical water-electrolysis in recent years is emphatically discussed, and the mechanisms of improving the performance of electrocatalysis is expounded by combining theoretical calculation technology and ex-situ/in situ characterization experiments. Finally, the application prospect of HEMs is proposed to conquer the challenges in HEM catalyst fabrications and applications.

关键词： high-entropy     electrocatalysis     synthetic methods     water-electrolysis     hydrogen and oxygen evolutions    

HTML PDF 收藏

A review of Pt-based electrocatalysts for oxygen reduction reaction

Changlin ZHANG, Xiaochen SHEN, Yanbo PAN, Zhenmeng PENG

《能源前沿（英文）》 2017年 第11卷 第3期   页码 268-285 doi: 10.1007/s11708-017-0466-6

摘要： Development of active and durable electrocatalyst for oxygen reduction reaction (ORR) remains one challenge for the polymer electrolyte membrane fuel cell (PEMFC) technology. Pt-based nanomaterials show the greatest promise as electrocatalyst for this reaction among all current catalytic structures. This review focuses on Pt-based ORR catalyst material development and covers the past achievements, current research status and perspectives in this research field. In particular, several important categories of Pt-based catalytic structures and the research advances are summarized. Key factors affecting the catalyst activity and durability are discussed. An outlook of future research direction of ORR catalyst research is provided.

关键词： oxygen reduction reaction (ORR)     electrocatalysis     platinum catalyst     activity     durability    

HTML PDF 收藏

Photoreduction adjusted surface oxygen vacancy of BiMoO for boosting photocatalytic redox performance

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 1937-1948 doi: 10.1007/s11705-023-2353-5

摘要： In this study, Bi2MoO6 with adjustable rich oxygen vacancies was prepared by a novel and simple solvothermal-photoreduction method which might be suitable for a large-scale production. The experiment results show that Bi2MoO6 with rich oxygen vacancies is an excellent photocatalyst. The photocatalytic ability of BMO-10 is 0.3 and 3.5 times higher than that of the pristine Bi2MoO6 for Rhodamine B degradation and Cr(VI) reduction, respectively. The results display that the band energy of the samples with oxygen vacancies was narrowed and the light absorption was broadened. Meanwhile, the efficiency of photogenerated electron-holes was increased and the separation and transfer speed of photogenerated carriers were improved. Therefore, this work provides a convenient and efficient method to prepare potential adjustable oxygen vacancy based photocatalysts to eliminate the pollution of dyes and Cr(VI) in water.

关键词： Bi2MoO6     oxygen vacancies     photoreduction     Cr(VI)     RhB    

HTML PDF 收藏

Role of oxygen vacancy inducer for graphene in graphene-containing anodes

《化学科学与工程前沿（英文）》 2023年 第17卷 第3期   页码 326-333 doi: 10.1007/s11705-022-2213-8

摘要： Currently, graphene is only considered as a conductive additive and expansion inhibitor in oxides/graphene composite anodes. In this study, a new graphene role (oxygen vacancy inducer) in graphene/oxides composites anodes, which are treated at high-temperature, is proposed and verified using experiments and density functional theory calculations. During high-temperature processing, graphene forms carbon vacancies due to increased thermal vibration, and the carbon vacancies capture oxygen atoms, facilitating the formation of oxygen vacancies in oxides. Moreover, the induced oxygen vacancy concentrations can be regulated by sintering temperatures, and the behavior is unaffected by oxide crystal structures (crystalline and amorphous) and morphology (size and shape). According to density functional theory calculations and electrochemical measurements, the oxygen vacancies enhance the lithium-ion storage performance. The findings can result in a better understanding of graphene’s roles in graphene/oxide composite anodes, and provide a new method for designing high-performance oxide anodes.

关键词： oxide     oxygen vacancy     graphene     anode     density functional theory calculation    

HTML PDF 收藏

Multivalent manganese oxides with high electrocatalytic activity for oxygen reduction reaction

Xiangfeng Peng, Zhenhai Wang, Zhao Wang, Yunxiang Pan

《化学科学与工程前沿（英文）》 2018年 第12卷 第4期   页码 790-797 doi: 10.1007/s11705-018-1706-y

摘要： A noble-metal-free catalyst based on both Mn O and MnO was prepared by using the dielectric barrier discharge technique at moderate temperature. The prepared catalyst shows a higher electrocatalytic activity towards the oxygen reduction reaction than the catalyst prepared by using the traditional calcination process. The enhanced activity could be due to the coexistence of manganese ions with different valences, the higher oxygen adsorption capacity, and the suppressed aggregation of the catalyst nanoparticles at moderate temperature. The present work would open a new way to prepare low-cost and noble-metal-free catalysts at moderate temperature for more efficient electrocatalysis.

关键词： oxygen reduction reaction     manganese oxides     mixed valences of manganese     oxygen adsorption     dielectric barrier discharge    

HTML PDF 收藏

标题 作者 时间 类型 操作

Experimental investigation on possibility of oxygen enrichment by using gradient magnetic fields

CAI Jun, WANG Li, TONG Lige, SUN Shufeng, WU Ping

期刊论文

using tower bipolar electro-flocculation including the removal of phosphorus, turbidity, sulfion, and oxygenenrichment

Huan He, Qinjin Yu, Chaochao Lai, Chen Zhang, Muhan Liu, Bin Huang, Hongping Pu, Xuejun Pan

期刊论文

Distribution, enrichment mechanism and risk assessment for fluoride in groundwater: a case study of Mihe-Weihe

期刊论文

Water Diversion is Not to Blame for Phosphorus Enrichment in Taihu Lake

Zhiyuan Wang,Qiuwen Chen,Jianyun Zhang,Hanlu Yan,

期刊论文

the effect of nitrogen on mixed culture polyhydroxyalkanoate production toward high organic loading enrichment

Zhiqiang Chen, Lizhi Zhao, Ye Ji, Qinxue Wen, Long Huang

期刊论文

Heterometallic cluster-based organic frameworks as highly active electrocatalysts for oxygen reductionand oxygen evolution reaction: a density functional theory study

期刊论文

Enrichment and transfer of polycyclic aromatic hydrocarbons (PAHs) through dust aerosol generation from

期刊论文

Mercury enrichment in

Chunhao Dai, Pufeng Qin, Zhangwei Wang, Jian Chen, Xianshan Zhang, Si Luo

期刊论文

Interface engineering for enhancing electrocatalytic oxygen evolution reaction of CoS/CeO heterostructures

期刊论文

页岩气主要富集因素与核心区选择及评价

王社教,杨涛,张国生,李登华,陈晓明

期刊论文

High-entropy catalysts for electrochemical water-electrolysis of hydrogen evolution and oxygen evolution

期刊论文

A review of Pt-based electrocatalysts for oxygen reduction reaction

Changlin ZHANG, Xiaochen SHEN, Yanbo PAN, Zhenmeng PENG

期刊论文

Photoreduction adjusted surface oxygen vacancy of BiMoO for boosting photocatalytic redox performance

期刊论文

Role of oxygen vacancy inducer for graphene in graphene-containing anodes

期刊论文

Multivalent manganese oxides with high electrocatalytic activity for oxygen reduction reaction

Xiangfeng Peng, Zhenhai Wang, Zhao Wang, Yunxiang Pan

期刊论文